A cost effective and environmentally friendly stormwater treatment method : The use of wood fly ash and H₂O₂

Abstract:

This current study is a lab-scale investigation focused on the treatment of stormwater runoff generated in wood-storage areas. The main target constituents of the proposed treatment were: metals (Cu, Cd, Co, V, Pb, Zn, Ni, Cr, Fe, As), COD, TOC, Phenols, and color. The method implemented for this project follows the main concept of using low-cost and environmentally friendly technologies and had as main steps the use of a by-product of wood-based industries - wood fly ashes as sorbents - followed by oxidation with H₂O₂ (Hydrogen Peroxide). The results obtained during this investigation were vey promising since satisfactory removal % was achieved. Removal rates of 98.5%, 86%, 89.6%, 79.6% were achieved for color, chemical oxygen demand (COD), total organic carbon (TOC) and phenols respectively. Furthermore a decrease in metals concentrations was also observed with the exception of chromium. The study showed that for 300 ml storm water, optimum conditions were with 7g wood fly ash, 5 hours time reaction, pH≈11.46 and 150 μl of a 30% H2O2 solution in a room temperature. To conclude it can be stated that the use of a by-product from wood industry to treat contaminated water from the same sector, following the concept of a closed-loop system, is promising and possible. However further studies need to be conducted in order to evaluate such system in scaled-up conditions.